What is the heat of solution?

What is the heat of solution?



Answer: Amount of heat absorbed or released when a solid dissolves

What can a Lewis acid do?

What can a Lewis acid do?



Answer: Accept a pair of electrons

Be able to define retention volume (Vr). What does a larger retention volume mean about a component's ability to interact with the liquid chromatography column?

Be able to define retention volume (Vr). What does a larger retention volume mean about a component's ability to interact with the liquid chromatography column?



A measure of the amount of mobile phase required to remove each component of the mixture from the column

Vr↑ = attracted to stationary phase

Vr↓ = attracted to mobile phase

Be able to name the mobile phase and stationary phases in your paper chromatography experiment and be able to use the "like dissolves like" principle to rationalize relative Rf values for dye molecules.

Be able to name the mobile phase and stationary phases in your paper chromatography experiment and be able to use the "like dissolves like" principle to rationalize relative Rf values for dye molecules.



mobile phase is solvent

stationary phase is the water

substances that follow "like dissolves like" with water will have a higher Rf value

Explain what is meant by a "back titration". Why is this a better approach than a regular titration for the analysis of calcium carbonate in egg shells. Be able to calculate the calcium carbonate content of an egg shell.

Explain what is meant by a "back titration". Why is this a better approach than a regular titration for the analysis of calcium carbonate in egg shells. Be able to calculate the calcium carbonate content of an egg shell.



Answer: A back titration is faster. Excess HCl is added to dissolve CaCO₃, then unreacted acid is titrated with a standard solution of base.

You used two different types of indicators in this experiment -- red cabbage extract, and bromothymol blue. Be able to cite one advantage of the BTB indicator over red cabbage.

You used two different types of indicators in this experiment -- red cabbage extract, and bromothymol blue. Be able to cite one advantage of the BTB indicator over red cabbage.



Answer: BTB will keep longer and the color change is instantaneous. RCE needs to be kept cool to prevent degradation.


Define the 4 major types of reactions that occur in aqueous solution and give an example of each type.

Define the 4 major types of reactions that occur in aqueous solution and give an example of each type.



1. Acid/Base: acids react with bases to produce salt and H2O.

2. Precipitation: forms an insoluble product.

3. Redox: chemical species changing oxidation states.

4. Complexation: form a complex ion (metal ion with other substances covalently bonded to it.

Write out chemical equations to explain why: 1. aqueous sodium carbonate is basic, 2. aqueous aluminum chloride is acidic, and 3. aqueous potassium iodide is neutral.

Write out chemical equations to explain why: 1. aqueous sodium carbonate is basic, 2. aqueous aluminum chloride is acidic, and 3. aqueous potassium iodide is neutral.



1. Na₂CO₃(aq) + 2 H₂O(l)→2 NaOH(aq) + CO₂(aq) + H₂O(l)


2. AlCl₃(aq) + 3 H₂O(l)→Al(OH)₃(aq) + 3 HCl(aq)


3. KI(aq) + H₂O(l)→KOH(aq) + HI(aq)

Use the "like dissolves like" principle to explain the solubility experiments that you did with ethanol, pentanol, kerosene, and water.

Use the "like dissolves like" principle to explain the solubility experiments that you did with ethanol, pentanol, kerosene, and water.



Answer: A small puddle of each substance was placed on the reaction surface. Next, a sample of KI was placed in each puddle. KI is ionic and polar so it would dissolve in polar solvents. The polarity of the solvents would be ranked bases on how quickly the KI dissolved.

In section B you tested for the presence of SO₄²⁻, K⁺, Al³⁺ and H₂O. Be able to explain how they were tested for and what should have been observed in each test.

In section B you tested for the presence of SO₄²⁻, K⁺, Al³⁺ and H₂O. Be able to explain how they were tested for and what should have been observed in each test.



Answer: Sulfate was tested for by reacting the alum with BaCl2. A white precipitate of BaSO4 formed. K and H2O were tested for by the flame test. The flame turned purple which shows K in it and a popping noise was heard as the water evaporated. Al was tested for by reacting it with KOH and checking for the Al(OH)4 precipitate and by Al having an acidic pH.

Given the overall reaction equation for the synthesis of alum and the molar masses involved, you should be able to calculate theoretical yield. If you are given the wt. of alum actually obtained, you should be able to calculate the % yield.

Given the overall reaction equation for the synthesis of alum and the molar masses involved, you should be able to calculate theoretical yield. If you are given the wt. of alum actually obtained, you should be able to calculate the % yield.



Answer: % yield = (g alum actually obtained / g alum theoretically produced) * 100 %

Be able to describe the observations of OTO (from Chlorine test kit) with tap water and water passed through a Brita filter. Explain.

Be able to describe the observations of OTO (from Chlorine test kit) with tap water and water passed through a Brita filter. Explain.

When tap water was reacted, the solution turned yellow due to the high chlorine ion concentration. The Brita water turned a lighter shade of yellow due to the Cl⁻ ions being removed. The Cl⁻ was removed because it stuck to the activated carbons which have tiny pores so there is a high surface area to react.


(a) Be able to estimate the standard deviation for a set of data using the "2/3's rule" described in this experiment. (b) Also, know how to calculate a standard deviation by hand for a given set of data.

(a) 1. put the number in increasing order.

2. Find the average of the numbers.

3. 2/3 * # of data points

4. + or - two points on either side of the average.

5. Report answer


(b) [(∑(x-x1)^2)/(N-1)]^.5

Describe the technique of colorimetry.

Describe the technique of colorimetry.



Answer: The process where a set of solutions of known concentrations of some light absorbing substance is placed in a series of containers. Unknown concentration solution can be determined by comparing with the calibration set.

If you are given the wavelengths of light observed by a particular student for the hydrogen emission spectrum you should be able to (a) determine the frequencies and energies associated with these wavelengths, (b) be able to use the Bohr equation to calculate the wavelengths expected for the Balmer series of the hydrogen atom, (c) be able to quantitatively compare the results from (a) and (b) - i.e., know how to calculate the % difference between a students results and Bohrs.

If you are given the wavelengths of light observed by a particular student for the hydrogen emission spectrum you should be able to (a) determine the frequencies and energies associated with these wavelengths, (b) be able to use the Bohr equation to calculate the wavelengths expected for the Balmer series of the hydrogen atom, (c) be able to quantitatively compare the results from (a) and (b) - i.e., know how to calculate the % difference between a students results and Bohrs.



(a) ∙frequency= speed of light/wavelength

∙energy= frequency x Planck's constant.

(b) ΔE= -Rn x (1/nf^2 - 1/ni^2)


(c) % difference = [(actual - theoretical)/ actual] x 100%

Outline in a few sentences how you calibrated your spectroscope.

Outline in a few sentences how you calibrated your spectroscope.



1. Spectroscope constructed.

2. Sample of excited hydrogen gas was viewed through spect.

3. It was noted what line on the graph paper in the spec. each line of H's spectra was on.

4. Plot the # of graph paper lines vs. actual wavelength and an equation was determined.

Describe what is meant by the term "white light," and know the wavelength range (in nm) that white light covers. List the colors of the spectrum from the highest to the lowest frequency.

Describe what is meant by the term "white light," and know the wavelength range (in nm) that white light covers. List the colors of the spectrum from the highest to the lowest frequency.



White light is apparent 'colorless' light from 400-750 nm. (Ex. light from the sun).

Lowest to highest: ROYGBV

Explain the difference between line and continuous spectrum, and give an example of a source of each type.

Explain the difference between line and continuous spectrum, and give an example of a source of each type.



Continuous: contains all the frequencies of the emitted radiation within a region on the EM spectrum. (Ex. the sun)


Line spectrum: only includes certain frequencies emitted by atoms in the gas phase and is produced by excited atoms. (Ex. gases)


When walking, an average person burns 0.453 Food Calories/mile-pounds. How many food calories does a 150-pound person burn after walking a mile? If a peanut releases 5.7 Food Calories/g and an average peanut weighs about 1 gram, then how many peanuts will you have to eat to walk a mile?

When walking, an average person burns 0.453 Food Calories/mile-pounds. How many food calories does a 150-pound person burn after walking a mile? If a peanut releases 5.7 Food Calories/g and an average peanut weighs about 1 gram, then how many peanuts will you have to eat to walk a mile?



(150 lb)∙(.453C/mi-lb)=67.95 C/mi


(67.95C/mi)∙(1g/ 5.7 C) = 12g = 12 peanuts

What is meant by a small calorie "c" and a food calorie "C"?

What is meant by a small calorie "c" and a food calorie "C"?



A small calorie "c" is a scientific calorie and it is 1000x smaller than a food calorie. Food calorie is 1000c and is how food is measured.


Write the name for FeS.

Write the name for FeS.



A) iron sulfide

B) iron (I) sulfide

C) iron (I) sulfate

D) iron (II) sulfide

E) iron (II) sulfate



Answer: D) iron (II) sulfide

Write a balanced equation to show the reaction of gaseous ethane with gaseous oxygen to form carbon monoxide gas and water vapor.

Write a balanced equation to show the reaction of gaseous ethane with gaseous oxygen to form carbon monoxide gas and water vapor.



A) 2 CH3 (g) + 5 O (g) → 2 CO (g) + 3 H2O (g)

B) C2H6 (g) + 7 O (g) → 2 CO2 (g) + 3 H2O (g)

C) 2 C2H6 (g) + 5 O2 (g) → 4 CO (g) + 6 H2O (g)

D) C2H6 (g) + 5 O (g) → 2 CO (g) + 3 H2O (g)

E) 2 C2H6 (g) + 7 O2 (g) → 4 CO2 (g) + 6 H2O (g)



Answer: (C) 2 C2H6 (g) + 5 O2 (g) → 4 CO (g) + 6 H2O (g)

When two elements form two different compounds, the masses of element B that combine with 1 g of element A can be expressed as a ratio of small whole numbers. Which law does this refer to?

When two elements form two different compounds, the masses of element B that combine with 1 g of element A can be expressed as a ratio of small whole numbers. Which law does this refer to?



A) Law of the Conservation of Mass

B) First Law of Thermodynamics

C) Law of Multiple Proportions

D) Law of Modern Atomic Theory

E) Law of Definite Proportions



Answer: C) Law of Multiple Proportions

How many Li atoms are contained in 97.9 g of Li?

How many Li atoms are contained in 97.9 g of Li?



A) 4.27 × 1022 Li atoms

B) 5.90 × 1025 Li atoms

C) 7.09 × 1021 Li atoms

D) 8.49 × 1024 Li atoms

E) 4.18 × 1024 Li atoms



Answer: D) 8.49 × 1024 Li atoms

Choose the element from the list below.

Choose the element from the list below.



A) carbon dioxide

B) rust

C) water

D) sodium chloride

E) helium



Answer: E) helium

Which of the following are examples of a chemical change?

Which of the following are examples of a chemical change?



A) coffee brewing

B) water boiling

C) salt dissolves in water

D) leaves turning color in the fall

E) None of the above are chemical changes.



Answer: D) leaves turning color in the fall

Which of the following represents a physical property?

Which of the following represents a physical property?



A) Aluminum has a tendency to "rust."

B) Mercury is a silvery liquid at room temperature.

C) Butane is highly flammable.

D) Sodium metal is extremely reactive with chlorine gas.

E) Argon has an unreactive nature.



Answer: B) Mercury is a silvery liquid at room temperature.

A student performs an experiment to determine the density of a sugar solution. She obtains the following results: 1.71 g/mL, 1.73 g/mL, 1.67 g/mL, 1.69 g/mL. If the actual value for the density of the sugar solution is 1.40 g/mL, which statement below best describes her results?

A student performs an experiment to determine the density of a sugar solution. She obtains the following results: 1.71 g/mL, 1.73 g/mL, 1.67 g/mL, 1.69 g/mL. If the actual value for the density of the sugar solution is 1.40 g/mL, which statement below best describes her results?



A) Her results are precise, but not accurate.

Her results are accurate, but not precise.

B) Her results are neither precise nor accurate.

C) Her results are both precise and accurate

D) It isn't possible to determine with the information given.



Answer: B) Her results are precise, but not accurate.

How does the monomer of polyvinyl chloride (PVC) differ from the monomer of polyethylene (PE)?

How does the monomer of polyvinyl chloride (PVC) differ from the monomer of polyethylene (PE)?



A) The PVC monomer has a chlorine atom, but the PE monomer does not.

B) The PVC monomer has two chlorine atoms, but the PE monomer does not.

C) The PE monomer has one chlorine atom, and the PVC monomer has two chlorine atoms.

D) The PVC monomer has a triple bond, and the PE monomer has a double bond.



Answer: A) The PVC monomer has a chlorine atom, but the PE monomer does not.

What is Teflon used for?

What is Teflon used for?



A) film

B) nonstick cookware

C) bullet-proof vests

D) garbage bags



Answer: B) nonstick cookware

A polymer that conducts electricity is

A polymer that conducts electricity is



A) polyacetylene.

B) polyethylene.

C) polyvinyl chloride.

D) polystyrene.



Answer: A) polyacetylene.

The monomer used to make PVC is

The monomer used to make PVC is



A) H2CCH2.

B) Cl2CCH2.

C) H2CCHCl.

D) F2CCF2.



Answer: C) H2CCHCl.

The monomer used to make Teflon is

The monomer used to make Teflon is



A) H2CCH2.

B) Cl2CCH2.

C) H2CCHCl.

D) F2CCF2.



Answer: D) F2CCF2.

Polyvinyl chloride is used for drain pipes in plumbing applications. It has replaced traditional cast iron pipe for this purpose. The major advantage of PVC in replacing cast iron for this application (particularly if you are a plumber or homeowner) is that PVC

Polyvinyl chloride is used for drain pipes in plumbing applications. It has replaced traditional cast iron pipe for this purpose. The major advantage of PVC in replacing cast iron for this application (particularly if you are a plumber or homeowner) is that PVC



A) is of lighter weight.

B) is easier to handle and cut.

C) is more resistant to corrosion.

D) All of the above are advantages of PVC.



Answer: D) All of the above are advantages of PVC.

The monomer of polypropylene is

The monomer of polypropylene is



A) CH2CH2.

B) CH2CHCH3.

C) CH3CH3.

D) CH3CH2CH3.



Answer: B) CH2CHCH3.

Which of the following statements about the difference between HDPE and LDPE is NOT correct?

Which of the following statements about the difference between HDPE and LDPE is NOT correct?



A) HDPE has a higher density than LDPE does.

B) HDPE holds its shape better than LDPE does when they are put into boiling water.

C) HDPE is more flexible than LDPE is.

D) HDPE has fewer side chains branching off from the main chains than LDPE does.



Answer: C) HDPE is more flexible than LDPE is.

Which of the following statements about ethylene and polyethylene is true?

Which of the following statements about ethylene and polyethylene is true?



A) The polymer has the same properties as the monomer.

B) The polymer has alternating double and single bonds between carbons, while the monomer has only single bonds between carbons.

C) The polymer has alternating double and single bonds between carbons, while the monomer has only double bonds between carbons.

D) The polymer has only single bonds between carbons, while the monomer has only double bonds between carbons.



Answer: D) The polymer has only single bonds between carbons, while the monomer has only double bonds between carbons.

A copolymer is composed of

A copolymer is composed of



A) two or more different monomers.

B) different polymers linked end to end.

C) different polymers cross-linked.

D) none of the above



Answer: A) two or more different monomers.

The most widely used synthetic polymer is

The most widely used synthetic polymer is



A) polyethylene.

B) polyvinyl chloride.

C) polystyrene.

D) polytetrafluoroethylene (Teflon).



Answer: A) polyethylene.

HDPE stands for

HDPE stands for



A) high-density polyethylene.

B) hot-dipped polyethylene.

C) high-dose polyethylene.

D) highly-diffuse polyethylene.



Answer: A) high-density polyethylene.

LDPE stands for

LDPE stands for



A) linearly dense polyethylene.

B) light diffuse polyethylene.

C) low-density polyethylene.

D) lightly doped polyethylene.



Answer: C) low-density polyethylene.

LDPE finds applications as

LDPE finds applications as



A) food wrap.

B) rigid containers.

C) drain pipes.

D) television cabinets.



Answer: A) food wrap.

HDPE finds applications in

HDPE finds applications in



A) food wrap.

B) rigid containers.

C) squeeze bottles.

D) garbage bags.



Answer: B) rigid containers.

Low-density polyethylene is composed of

Low-density polyethylene is composed of



A) primarily linear, unbranched chains of polyethylene in a close packing arrangement.

B) primarily highly branched, non-linear chains of polyethylene in a diffuse packing arrangement.

C) a mixture of polyethylene and polystyrene.

D) polyethylene with low density plasticizers added to increase density.



Answer: B) primarily highly branched, non-linear chains of polyethylene in a diffuse packing arrangement.

High-density polyethylene is composed of

High-density polyethylene is composed of



A) primarily linear, unbranched chains of polyethylene in a close packing arrangement.

B) primarily highly branched, non-linear chains of polyethylene in a diffuse packing arrangement.

C) a mixture of polyethylene and polystyrene.

D) polyethylene with high density plasticizers added to increase density.



Answer: A) primarily linear, unbranched chains of polyethylene in a close packing arrangement.

Which statement relating monomers and polymers is correct?

Which statement relating monomers and polymers is correct?



A) They have the same chemical and physical properties.

B) They have different chemical and physical properties.

C) The monomer is usually a solid, while the polymer is usually a liquid or gas.

D) They have the same chemical formula.



Answer: B) They have different chemical and physical properties.

The word monomer means

The word monomer means



A) one bond.

B) one unit.

C) many bonds.

D) many rings.



Answer: B) one unit.

The word polymer means many

The word polymer means many



A) parts.

B) sides.

C) rings.

D) carbons.



Answer: A) parts.

Monomers are

Monomers are



A) small building blocks of polymers.

B) small polymers.

C) ethylene.

D) all of the above



Answer: A) small building blocks of polymers.

All antacids are

All antacids are



A) acids.

B) bases.

C) neutral.

D) salts.



Answer: B) bases.

Sodium bicarbonate is commonly known as

Sodium bicarbonate is commonly known as



A) baking soda.

B) baking powder.

C) washing soda.

D) cherry soda.



Answer: A) baking soda.

By definition, acid rain has a pH

By definition, acid rain has a pH



A) below 4.

B) below 5.6.

C) below 7.

D) above 8.5



Answer: B) below 5.6.

Which of the following does NOT contribute to acid rain?

Which of the following does NOT contribute to acid rain?



A) coal-burning power plants

B) lightning

C) volcanic eruptions

D) All of the above contribute to acid rain.



Answer: D) All of the above contribute to acid rain.

A buffer

A buffer



A) resists changes in pH when small amounts of a strong acid or a strong base are added.

B) is made up of a weak acid and its conjugate base.

C) is made up of a weak base and its conjugate acid.

D) All of the above are true.



Answer: D) All of the above are true.

Which substance has the lowest pH?

Which substance has the lowest pH?



A) blood

B) lemon juice

C) unpolluted rainwater

D) NaOH (4% solution)



Answer: B) lemon juice

A weak base

A weak base



A) is present in low concentration in solution.

B) is present in high concentration in solution.

C) ionizes only slightly in solution.

D) ionizes completely in solution.



Answer: C) ionizes only slightly in solution.

Nitrous acid, HNO2, is classified as a weak acid in water. This means that it produces

Nitrous acid, HNO2, is classified as a weak acid in water. This means that it produces



A) no hydronium ions.

B) a relatively small fraction of the maximum number of possible hydronium ions.

C) a relatively large fraction of the maximum number of possible hydronium ions.

D) 100% of the maximum number of possible hydronium ions.



Answer: B) a relatively small fraction of the maximum number of possible hydronium ions.

An acid is strong if it

An acid is strong if it



A) is very concentrated.

B) makes acid-base indicators change color.

C) ionizes completely in water.

D) causes metals to corrode.



Answer: C) ionizes completely in water.

All of the following are strong acids EXCEPT

All of the following are strong acids EXCEPT



A) hydrochloric acid.

B) sulfuric acid.

C) nitric acid.

D) acetic acid.



Answer: D) acetic acid.

Sodium hydroxide is classified as a strong base in water. This means that it produces

Sodium hydroxide is classified as a strong base in water. This means that it produces



A) no hydroxide ions.

B) a relatively small fraction of the maximum number of possible hydroxide ions.

C) a relatively large fraction of the maximum number of possible hydroxide ions.

D) 100% of the maximum number of possible hydroxide ions.



Answer: D) 100% of the maximum number of possible hydroxide ions.

Ammonia is classified as a weak base in water. This means that it produces

Ammonia is classified as a weak base in water. This means that it produces



A) no hydroxide ions.

B) a relatively small fraction of the maximum number of possible hydroxide ions.

C) a relatively large fraction of the maximum number of possible hydroxide ions.

D) 100% of the maximum number of possible hydroxide ions.



Answer: B) a relatively small fraction of the maximum number of possible hydroxide ions.

Nitric acid, HNO3, is classified as a strong acid in water. This means that it produces

Nitric acid, HNO3, is classified as a strong acid in water. This means that it produces



A) no hydronium ions.

B) a relatively small fraction of the maximum number of possible hydronium ions.

C) a relatively large fraction of the maximum number of possible hydronium ions.

D) 100% of the maximum number of possible hydronium ions.



Answer: D) 100% of the maximum number of possible hydronium ions.

HCN is classified as a weak acid in water. This means that it produces

HCN is classified as a weak acid in water. This means that it produces



A) no hydronium ions.

B) a relatively small fraction of the maximum number of possible hydronium ions.

C) a relatively large fraction of the maximum number of possible hydronium ions.

D) 100% of the maximum number of possible hydronium ions.



Answer: B) a relatively small fraction of the maximum number of possible hydronium ions.

The same number of moles of acetic acid and hydrogen chloride are placed in beakers containing water. After this addition, the beaker with the HCl has more hydronium ions than the beaker with added acetic acid. HCl is classified as

The same number of moles of acetic acid and hydrogen chloride are placed in beakers containing water. After this addition, the beaker with the HCl has more hydronium ions than the beaker with added acetic acid. HCl is classified as



A) a weaker acid than acetic acid.

B) a stronger acid than acetic acid.

C) equal in acid strength to acetic acid.

D) a base.



Answer: B) a stronger acid than acetic acid.

H3O+ is the

H3O+ is the



A) hydrate ion.

B) hydrogen ion.

C) hydroxide ion.

D) hydronium ion.



Answer: D) hydronium ion.

Which of the following is NOT true of the Arrhenius theory?

Which of the following is NOT true of the Arrhenius theory?



A) Acids are defined as compounds that produce H+ ions in water solution.

B) Bases are defined as compounds that produce OH- ions in water solution.

C) Arrhenius theory only applies to reactions in aqueous solution.

D) Acids are defined as compounds that produce OH- ions in water solution.



Answer: D) Acids are defined as compounds that produce OH- ions in water solution.

Which of the following is/are characteristic(s) of bases?

Which of the following is/are characteristic(s) of bases?



A) taste bitter

B) reacts with acids to form salts

C) produce hydroxide ions when added to water

D) All are characteristics of bases.



Answer: D) All are characteristics of bases.

Which of the following is/are characteristic(s) of acids?

Which of the following is/are characteristic(s) of acids?



A) taste sour

B) turn litmus red

C) react with bases to form salts

D) All are characteristics of acids.



Answer: D) All are characteristics of acids.

Which is NOT a characteristic of bases?

Which is NOT a characteristic of bases?



A) taste bitter

B) turn litmus red

C) react with acids to form salts

D) produce hydroxide ions when added to water



Answer: B) turn litmus red

Which is NOT a characteristic of acids?

Which is NOT a characteristic of acids?



A) taste bitter

B) turn litmus red

C) react with bases to form salts

D) react with active metals to form H2 gas



Answer: A) taste bitter